VALVOLINE CO -- NAPA ANTIFREEZE COOLANT  -- 6850-00N073626
<pre>=====================  Product Identification  =====================

Product ID:NAPA ANTIFREEZE COOLANT
MSDS Date:05/07/1996
FSC:6850
NIIN:00N073626
=== Responsible Party ===
Company Name:VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Info Phone Num:606-357-7847
Emergency Phone Num:800-274-5263
CAGE:IO754
=== Contractor Identification ===
Company Name:THE VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7847
CAGE:IO754
Company Name:VALVOLINE OIL CO
Address:3499 BLAZER PKY
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7206 / 800-274-5263
CAGE:72527

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 83%
OSHA PEL:N/K 
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 6-16%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:POTASSIUM PHOSPHATE
CAS:7758-11-4
Fraction by Wt: 0.0-7.0%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT: BASED ON POSITIVE TEST RESULTS WITH LAB ANIMALS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: VOMIT BY GIVING SYRUP OF IPECAC/BY GENTLY
    PLACING 2 FINGERS AT BACK OF THROAT. IF POSS, DO NOT (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:LEAVE UNATTENDED. INHAL:IF SYMPS DEVELOP, IMMED MOVE
    AWAY FROM EXPOS & INTO FRESH AIR. SEEK IMMED MED ATTN;(ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: KEEP PERSON WARM & QUIET. IF NOT BRTHG, BEGIN ARTF
    RESP. IF BRTHG IS DFCLT, ADMIN OXYGEN. NOTE TO MD:PROD (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: CNTNS ETHYLENE GLYCOL. ETHANOL DECRS METABOLISM OF
    ETHYLENE GLYCOL TO TOX METABOLITES. ETHANOL SHOULD BE (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: ADMIN AS SOON AS POSS IN CASES OF SEV POISONING
    SINCE ELIM HALF-LIFE OF ETHYLENE GLYCOL IS 3 HRS. IF MED (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:CARE WILL BE DELAYED SEVERAL HRS, USE THREE TO FOUR
    1-OZ ORAL "SHOTS" OF 86-PROOF/HIGHER WHISKEY BEFORE (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: OR DURING TRANSPORT TO HOSPITAL. HEMODIALYSIS
    EFTIVELY REMOVES ETHYLENE GLYCOL & ITS METABOLITES FROM THE BODY.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: PUMP LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE
    TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB OR OTHER (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: ABSORB MATL & SHOVELED INTO CNTNRS.
RTECS #:9999999ZZ

Ingred Name:RESP PROT: INDUSTRIAL HYGIENIST). ENGINEERING OR
    ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURES.
RTECS #:9999999ZZ

Ingred Name:PROT GLOVES: NITRILE, NITRILE RUBBER, POLYVINYL CHLORIDE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYE:EXPOS MAY CAUSE MILD IRRIT. SYMPS
    MAY INCL STINGING, TEARING & REDNESS. SKIN:EXPOS MAY CAUSE MILD
    IRRIT. SYMPS MAY INCL REDNESS & BURNING. INGEST:SINGLE DOSE ORAL
    TOX IS LOW. SWALLOWING SM AMTS DU RING NORM HNDLG IS NOT LIKELY TO
    CAUSE HARMFUL EFTS; SWALLOWING LG AMTS MAY BE HARMFUL. INHAL:EXPOS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: TO VAP/MIST IS POSS. SYMPS OF EXPOS:
    GI IRRIT (NAUS, VOMIT, DIARR), IRRIT (NOSE, THROAT, RESP TRACT),
    CNS DEPRESS (DIZZ, DROW, WEAK, FATG, NAUS, HDCH, UNCON), KIDNEY
    DMG. OVEREXP TO MATL (OR  ITS COMPONENTS) HAS BEEN SUGGESTED AS A
    CAUSE OF FOLLOWING EFTS IN LAB ANIMALS & MAY AGGRAVATE PRE-EXISTING
    (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISORDERS, EG
    ASTHMA-LIKE CONDITIONS, MAY BE AGGRAVATED BY EXPOSURE TO THIS
    MATERIAL.

=======================  First Aid Measures  =======================

First Aid:EYES:IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
    GENTLY W/WATER FOR AT LEAST 15 MIN WHILE HOLDING LIDS APART; SEEK
    IMMED MED ATTN. SKIN:REMOVE CONTAMD CLTHG. WASH EXPOSED AREA W/SOAP
    & WATER. I F SYMPS PERSIST, SEEK MED ATTN. LAUNDERCLTHG BEFORE
    REUSE. INGEST:SEEK MED ATTN. IF DROWSY/UNCON, DO NOT GIVE ANYTHING
    BY MOUTH; PLACE ON LEFT SIDE W/HEAD DOWN. IF CONSCIOUS & ALERT,
    INDUCE (ING 5)

=====================  Fire Fighting Measures  =====================

Flash Point Method:COC
Flash Point:250F,121C
Lower Limits:3.2%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT . REFER TO PERSONAL PROTECTIVE EQUIPMENT SECTION OF MSDS.
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
    DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE
    EXPLO. COMBUST MAY FORM CARBON DIOXIDE & CARBON (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:SM SPILL:ABSORB LIQ ON VERMICULITE, FLOOR
    ABSORB/OTHER ABSORB MATL. LG SPILL:PERS NOT WEARING PROT EQUIP
    SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN
    COMPLETED. STOP SPILL AT SOURCE,  DIKE AREA OF SPILL TO PVNT
    SPREADING, (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN
    EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR
    SOLID), ALL HAZ PRECS GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
    IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE
    OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPS (NEG
    PRESS TYPE) UNDER  SPECIFIED CNDTNS (CONSULT (ING 14)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
    VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESIST GLOVES SUCH AS: NEOPRENE (ING 15)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . TO
    PREVENT RPTD/PRLNGD SKIN CONTACT WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: MONOXIDE, VARIOUS HYDROCARBS. EFTS OF OVEREXP:DISORDERS OF
    THESE ORGANS IN HUMANS:KIDNEY DMG; IT HAS BEEN SUGGESTED AS A CAUSE
    OF FOLLOWING EFTS IN HUMANS & MAY AGGRAVATE PRE-EXISTING DISOR DERS
    OF THESE ORGANS: CNS EFTS, LIVER ABNORMS, KIDNEY DMG. MATL (OR
    COMPONENT) MAY CAUSE BIRTH DEFECTS IN HUMANS (ING 4)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:330F,166C
Vapor Pres:0.800 @68F
Vapor Density:>1
Spec Gravity:1.135
pH:9-11
Appearance and Odor:GREEN LIQUID; FAINT GLYCOL ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
    MONOXIDE, VARIOUS HYDROCARBONS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DESTROY BY LIQUID INCINERATION. DISPOSE OF IN
    ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
    REGULATIONS.

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